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  • Position-selective intramolecular aromatic C-H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(II) complexes.

Position-selective intramolecular aromatic C-H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(II) complexes.

Dalton transactions (Cambridge, England : 2003) (2012-12-14)
Kenichi Ogata, Sayuri Inomata, Shin-ichi Fukuzawa
ABSTRACT

A series of 1,2,3-triazol-5-ylidene (tzNHC) complexes of a (p-cymene)ruthenium system was synthesized. The reactivity of the N-bonded and C-bonded aryl groups in the tzNHC ligand was found to be significantly different with respect to intramolecular aromatic C-H bond activation.

MATERIALS
Product Number
Brand
Product Description

Supelco
p-Cymene, certified reference material, TraceCERT®
Sigma-Aldrich
p-Cymene, 99%
Supelco
p-Cymene, analytical standard