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  • Base- and metal-free C-H direct arylations of naphthalene and other unbiased arenes with diaryliodonium salts.

Base- and metal-free C-H direct arylations of naphthalene and other unbiased arenes with diaryliodonium salts.

Chemical communications (Cambridge, England) (2012-08-03)
Susana Castro, Juan J Fernández, Rubén Vicente, Francisco J Fañanás, Félix Rodríguez
ABSTRACT

A novel metal-free direct arylation of unbiased arenes with diaryliodonium triflates in a process where the use of solvents and additives is not required has been established.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Diphenyliodonium p-toluenesulfonate, electronic grade, ≥99% trace metals basis
Sigma-Aldrich
Diphenyliodonium nitrate
Sigma-Aldrich
Diphenyliodonium chloride, ≥98.0% (AT)
Sigma-Aldrich
Diphenyliodonium hexafluorophosphate, ≥98%