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Observation of NMR noise from solid samples.

Journal of magnetic resonance (San Diego, Calif. : 1997) (2010-09-21)
Judith Schlagnitweit, Jean-Nicolas Dumez, Martin Nausner, Alexej Jerschow, Bénédicte Elena-Herrmann, Norbert Müller
ABSTRACT

We demonstrate that proton NMR noise signals, i.e. NMR spectra without excitation by radio frequency, can be obtained from solid samples. Experimental results are shown for static and magic-angle spinning conditions. In addition, a tuning procedure based on the probes' NMR noise characteristics and similar to the one described previously for liquids probes can also be used to optimize signal-to-noise ratios in ¹H-MAS experiments.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Hexamethylbenzene, purified by sublimation, ≥99%
Sigma-Aldrich
Hexamethylbenzene, 99%