Skip to Content
Merck
  • Synthesis and catalytic properties of mesoporous, bifunctional, gallium-niobium mixed oxides.

Synthesis and catalytic properties of mesoporous, bifunctional, gallium-niobium mixed oxides.

Chemical communications (Cambridge, England) (2010-08-18)
Chinmay A Deshmane, Jacek B Jasinski, Paul Ratnasamy, Moises A Carreon
ABSTRACT

Thermally stable mesoporous Ga-Nb mixed oxides, active in both acid-catalysed and redox reactions have been synthesized via self-assembly hydrothermal assisted approach. Methyl oleate, a major component of biodiesels, undergoes double bond and skeletal isomerisation as well as dehydrogenation over these novel mesophases.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Methyl elaidate, ≥99% (capillary GC)
Supelco
Methyl elaidate, analytical standard
Supelco
cis-9-Octadecenoic acid methyl ester, certified reference material, 10 mg/mL in heptane
Sigma-Aldrich
Methyl oleate, technical grade, 70%
Sigma-Aldrich
Methyl oleate, 99%
Supelco
Methyl oleate, analytical standard