- Monosaccharides as internal probes for the determination of the absolute configuration of 2-butanol.
Monosaccharides as internal probes for the determination of the absolute configuration of 2-butanol.
Magnetic resonance in chemistry : MRC (2005-12-17)
Patrycja Seroka, Marcin Płosiński, Jacek Czub, Paweł Sowiński, Jan Pawlak
PMID16358294
ABSTRACT
D-Glucose, D-mannose and L-rhamnose were reacted with a racemic mixture of 2-butanol, and the resulting alpha-glycosides were analyzed by 1H NMR with COSY and NOESY experiments. Conformational analysis of alpha-glycosidic bonds performed with molecular modeling and appropriate heteronuclear long-range coupling measurements and combined with analysis of dipolar couplings observed in NOESY spectra allowed the assignment of absolute configuration in the aglycones of elucidated alpha-glycosides.
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