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  • Enantioseparation of atropisomeric 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate in capillary electrophoresis by using di- and oligosaccharides as chiral selectors: di- and oligosaccharide chiral selectors in capillary electrophoresis.

Enantioseparation of atropisomeric 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate in capillary electrophoresis by using di- and oligosaccharides as chiral selectors: di- and oligosaccharide chiral selectors in capillary electrophoresis.

Chirality (1998-02-21)
B Chankvetadze, M Saito, E Yashima, Y Okamoto
ABSTRACT

Twelve different disaccharides and a series of noncyclic malto- and cello-oligosaccharides were used as chiral selectors in capillary electrophoresis (CE). Most saccharides resolved the enantiomers of atropisomeric 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate (BDHP) depending on the type (alpha or beta) and position of the linkage between monosaccharides. The effect of chain length of malto- and cello-oligosaccharides on enantioseparation of BDHP was also investigated. The nature of cations in background electrolytes affected significantly the separation of BDHP enantiomers.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate, 95%
Sigma-Aldrich
(R)-(−)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate, ≥98%
Sigma-Aldrich
(S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate, 97%