sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

GF44280974

Nickel, rod, 200mm, diameter 40mm, 99%

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

GF46969587

Nickel, wire reel, 5m, diameter 0.5mm, as drawn, 99%

GF84292364

Nickel, wire reel, 2m, diameter 0.75mm, as drawn, 99.99+%

GF54123476

Nickel, wire reel, 500m, diameter 0.125mm, hard, 99.98%

GF13887546

Nickel, foil, 6mm disks, thickness 0.007mm, 99.95%

GF39981437

Nickel, wire reel, 5m, diameter 0.25mm, as drawn, 99.99+%

GF04942414

Nickel, wire reel, 5m, diameter 0.5mm, hard, 99.98%

GF09192315

Nickel, wire reel, 5m, diameter 0.05mm, as drawn, 99.99+%

GF39346038

Nickel, foil, 6mm disks, thickness 0.015mm, 99.9%

GF07174762

Nickel, foil, 6mm disks, thickness 0.05mm, annealed, 99%

GF57702348

Nickel, wire reel, 500m, diameter 0.25mm, hard, 99.98%

GF83400364

Nickel, foil, not light tested, 100x100mm, thickness 0.002mm, 99.95%

GF89307063

Nickel, foil, not light tested, 25x25mm, thickness 0.001mm, 99.95%

GF92543564

Nickel, foil, 150x300mm, thickness 0.25mm, annealed, 99.98%

GF13212807

Nickel, pellets, 50g, max. size 5mm, 99.99+%

GF39653310

Nickel, wire reel, 0.5m, diameter 0.05mm, as drawn, 99.99+%

GF56798847

Nickel, foil, 4mm disks, thickness 0.02mm, 99.9%

GF56028720

Nickel, foil, 0.5m coil, thickness 0.038mm, 99.9%

GF60017510

Nickel, foil, 0.2m coil, thickness 0.004mm, hard, 99%

GF22004334

Nickel, foil, 150x300mm, thickness 0.5mm, annealed, 99.98%

GF97080149

Nickel, foil, 10mm disks, thickness 0.0125mm, 99.9%

GF16075638

Nickel, foil, 0.5m coil, thickness 0.15mm, coil width 12mm, annealed, 99%

GF51837093

Nickel, foil, 50x50mm, thickness 1.0mm, annealed, 99%

GF71077136

Nickel, foil, 25x25mm, thickness 3.2mm, as rolled, 99.99+%