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15461

Sigma-Aldrich

Boc-Met-OSu

Synonym(s):

Boc-L-methionine hydroxysuccinimide ester

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About This Item

Empirical Formula (Hill Notation):
C14H22N2O6S
CAS Number:
3845-64-5
Molecular Weight:
346.40
Beilstein:
4238574
EC Number:
223-341-9
MDL number:
MFCD00042760
UNSPSC Code:
12352209
PubChem Substance ID:
57647441
NACRES:
NA.22

form

solid

optical activity

[α]20/D −21.5±2°, c = 2% in dioxane

reaction suitability

reaction type: Boc solid-phase peptide synthesis

ign. residue

≤0.05%

mp

120-128 °C

application(s)

peptide synthesis

storage temp.

−20°C

SMILES string

CSCC[C@H](NC(=O)OC(C)(C)C)C(=O)ON1C(=O)CCC1=O

InChI

1S/C14H22N2O6S/c1-14(2,3)21-13(20)15-9(7-8-23-4)12(19)22-16-10(17)5-6-11(16)18/h9H,5-8H2,1-4H3,(H,15,20)/t9-/m0/s1

InChI key

PCZJWSPKNYONIM-VIFPVBQESA-N

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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C W Basse et al.
The Journal of biological chemistry, 268(20), 14724-14731 (1993-07-15)
We have previously isolated glycopeptides derived from yeast invertase that acted as highly potent elicitors in suspension-cultured tomato cells, inducing ethylene biosynthesis and phenylalanine ammonia-lyase activity, and we have found that the high mannose oligosaccharides released from the pure glycopeptide
F Z Sheabar et al.
Chemical research in toxicology, 7(5), 650-658 (1994-09-01)
We report the chemical foundation for a new method to detect carcinogen-DNA adducts, which we have designated adduct detection by acylation with methionine (ADAM). The method is based on reaction of DNA adducts with a protected methionine derivative, (tert-butoxycarbonyl)-L-methionine N-hydroxysuccinimidyl

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