sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

357634

Sigma-Aldrich

Nickel, wire, diam. 0.25 mm, ≥99.9%

221678

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 2800, slurry, in H₂O, active catalyst

268259

Sigma-Aldrich

Nickel, foil, thickness 0.125 mm, ≥99.9%

267007

Sigma-Aldrich

Nickel, foil, thickness 0.25 mm, 99.995% trace metals basis

267058

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.99% trace metals basis

268283

Sigma-Aldrich

Nickel, powder, <1 μm, 99.8% trace metals basis

510033

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 2400, slurry, in H₂O, active catalyst

203904

Sigma-Aldrich

Nickel, powder, <150 μm, 99.99% trace metals basis

510068

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 3202, slurry, in H₂O, active catalyst

510041

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 4200, slurry, in H₂O, active catalyst

GF18961960

Nickel, tube, 200mm, outside diameter 1.3mm, inside diameter 1.1mm, wall thickness 0.1mm, hard, 99.5%

GF05980754

Nickel, tube, 500mm, outside diameter 0.8mm, inside diameter 0.3mm, wall thickness 0.25mm, as drawn, 99.5%

GF28279840

Nickel, foil, 25mm disks, thickness 0.008mm, 99.95%

GF95347110

Nickel, tube, 500mm, outside diameter 0.762mm, inside diameter 0.204mm, wall thickness 0.279mm, hard, 99.5%

GF97622815

Nickel, tube, 200mm, outside diameter 2.5mm, inside diameter 2.25mm, wall thickness 0.125mm, hard, 99.5%

GF97079912

Nickel, wire reel, 5m, diameter 0.4mm, as drawn, 99.99+%

GF95500593

Nickel, wire reel, 50m, diameter 0.4mm, as drawn, 99%

GF80039538

Nickel, wire reel, 2m, diameter 0.5mm, hard, 99.98%

GF46862332

Nickel, foil, 25mm disks, thickness 0.0025mm, 99.95%

GF01529423

Nickel, wire reel, 5m, diameter 0.75mm, as drawn, 99%

GF39747224

Nickel, wire reel, 50m, diameter 2.0mm, hard, 99.98%

GF93039633

Nickel, wire reel, 200m, diameter 0.125mm, annealed, 99.98%

GF15429595

Nickel, tube, 200mm, outside diameter 6.5mm, inside diameter 5.5mm, wall thickness 0.5mm, hard, 99.5%

GF26431871

Nickel, wire reel, 20m, diameter 0.125mm, as drawn, 99%

GF65063628

Nickel, foil, 25mm disks, thickness 0.009mm, 99.95%

GF54898419

Nickel, tube, 200mm, outside diameter 2.5mm, inside diameter 2mm, wall thickness 0.25mm, hard, 99.5%

GF06866770

Nickel, tube, 500mm, outside diameter 0.78mm, inside diameter 0.2mm, wall thickness 0.29mm, as drawn, 99.5%

GF97647845

Nickel, tube, 200mm, outside diameter 0.8mm, inside diameter 0.3mm, wall thickness 0.25mm, as drawn, 99.5%

GF64122094

Nickel, wire reel, 250m, diameter 0.125mm, as drawn, 99%

GF11232694

Nickel, wire reel, 5m, diameter 0.25mm, as drawn, 99%