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Expedient Route to the functionalized calyciphylline A-type skeleton via a Michael addition-RCM strategy.

Organic letters (2011-09-09)
Filippo Sladojevich, Iacovos N Michaelides, Darses Benjamin, John W Ward, Darren J Dixon
RESUMEN

An efficient, robust, and scalable strategy to access the functionalized core of calyciphylline A-type alkaloids has been developed starting from commercially available 3-methylanisole. Key features of this approach are an intramolecular Michael addition/allylation sequence and a ring-closing metathesis step.

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Sigma-Aldrich
3-Methylanisole, 99%