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H11300

Sigma-Aldrich

Hexamethylenetetramine

ReagentPlus®, 99%

Sinónimos:

1,3,5,7-Tetraazatricyclo[3.3.1.13,7]decane, Hexamine, Methenamine, Urotropine

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About This Item

Fórmula empírica (notación de Hill):
C6H12N4
Número de CAS:
100-97-0
Peso molecular:
140.19
Beilstein/REAXYS Number:
2018
EC Number:
202-905-8
MDL number:
MFCD00006895
UNSPSC Code:
12352100
PubChem Substance ID:
57654228
NACRES:
NA.21

vapor pressure

<0.01 mmHg ( 20 °C)

Quality Level

200

product line

ReagentPlus®

assay

99%

autoignition temp.

770 °F

mp

280 °C (subl.) (lit.)

solubility

H2O: soluble

SMILES string

C1N2CN3CN1CN(C2)C3

InChI

1S/C6H12N4/c1-7-2-9-4-8(1)5-10(3-7)6-9/h1-6H2

InChI key

VKYKSIONXSXAKP-UHFFFAOYSA-N

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General description

Hexamethylenetetramine (HMT), a water-soluble and cage-like organic building block, is employed to form novel coordination polymers. Its ability to inhibit the corrosion of mild steel in sulfuric acid solution has been investigated. The piezoelectric effect observed in the crystals of HMT has been analyzed. The preparation of certain binary, ternary and quaternary metal oxides via solution combustion technique using HMT as a fuel has been described.

Application

Hexamethylenetetramine may be used to synthesize:
  • nitrogen-doped yellowish rutile titania
  • nitrogen-doped graphene sheets (NGS)
  • highly stable graphene aqueous dispersions

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

hcodes

H228,H317

Hazard Classifications

Flam. Sol. 2 - Skin Sens. 1B

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 1

flash_point_f

482.0 °F - closed cup

flash_point_c

250 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
SDBB0458
STBL3592
STBK6244
STBK9642
STBK8226

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Stable aqueous dispersions of graphene prepared with hexamethylenetetramine as a reductant.
Shen X, et al.
Journal of Colloid and Interface Science, 354(2), 493-497 (2011)
Hexamethylenetetramine: an old new building block for design of coordination polymers.
Kirillov AM.
Coordination Chemistry Reviews, 255(15), 1603-1622 (2011)
Synergism and antagonism in mild steel corrosion inhibition by sodium dodecylbenzenesulphonate and hexamethylenetetramine.
Hosseini M, et al.
Corrosion Science, 45(7), 1473-1489 (2003)
Hexamethylenetetramine: a new fuel for solution combustion synthesis of complex metal oxides.
Prakash AS, et al.
J. Mater. Synth. Process, 10(3), 135-141 (2002)
Hydrothermal preparation of nitrogen-doped graphene sheets via hexamethylenetetramine for application as supercapacitor electrodes.
Lee JW, et al.
Electrochimica Acta, 85, 459-466 (2012)
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