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Key Documents

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W442600

Sigma-Aldrich

Methyl isothiocyanate

97%

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About This Item

Fórmula lineal:
CH3NCS
Número de CAS:
556-61-6
Peso molecular:
73.12
FEMA Number:
4426
Beilstein/REAXYS Number:
605319
EC Number:
209-132-5
MDL number:
MFCD00004818
UNSPSC Code:
12164502
PubChem Substance ID:
329830716

biological source

synthetic

vapor pressure

21 mmHg ( 20 °C)

assay

97%

bp

117-118 °C (lit.)

mp

30-34 °C (lit.)
34-36 °C

density

1.069 g/cm3 at 25 °C (lit.)

application(s)

flavors and fragrances

documentation

see Safety & Documentation for available documents

food allergen

no known allergens

organoleptic

pungent

SMILES string

CN=C=S

InChI

1S/C2H3NS/c1-3-2-4/h1H3

InChI key

LGDSHSYDSCRFAB-UHFFFAOYSA-N

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signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

86.0 °F - closed cup

flash_point_c

30 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
MKBD1869
MKBB7434

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William S Cain et al.
Regulatory toxicology and pharmacology : RTP, 58(2), 173-180 (2010-07-17)
An unpublished laboratory study by Russell and Rush (1996) showed that human subjects sense the presence of methyl isothiocyanate (MITC) via the eyes at concentrations as low as hundreds of ppb in air, with dependence upon duration of exposure. The
YongLin Ren et al.
Pest management science, 68(2), 194-201 (2011-07-23)
Methyl bromide is being phased out for use on stored commodities, as it is listed as an ozone-depleting substance, and phosphine is the fumigant widely used on grains. However, phosphine resistance occurs worldwide, and phosphine fumigation requires a long exposure
Yonglin Ren et al.
Journal of economic entomology, 101(2), 623-630 (2008-05-08)
Australian Standard White wheat, Triticum aestivum L. (a marketing grade with mixed grain hardness),with a moisture content of 12.5% was fumigated with a new ethyl formate formulation (95% ethyl formate plus 5% methyl isothiocyanate) identified and developed by Commonwealth Scientific
S Chen
Biomedical chromatography : BMC, 20(8), 718-728 (2005-10-18)
Amino acids were derivatized with sulfur-containing reagents in alkaline medium and enantioresolved by HPLC on a teicoplanin chiral stationary phase. Much better resolution was achieved using methanol-based mobile phase compared with elution with acetonitrile-based solvent mixture. The value of selectivity
Y Zhang et al.
Journal of environmental quality, 34(5), 1566-1572 (2005-08-11)
Recent studies have observed enhanced degradation of methyl isothiocyanate (MITC) from repeated fumigation in agricultural soils. Little is known about fumigant degradation in forest and nursery soils. This study was conducted to determine degradation rates of MITC and chloropicrin (CP)
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