- Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes.
Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes.
Inorganic chemistry (2007-12-07)
Ariela W Kaspi, Anette Yahav-Levi, Israel Goldberg, Arkadi Vigalok
PMID18052157
ABSTRACT
Palladium(II) aryliodo complexes bearing chelating diphosphine ligands react with XeF2, giving iodoarene and rare palladium(II) difluoro complexes. The reaction is general with regard to the aryl group, with even C6F5-I undergoing facile reductive elimination from a Pd center.
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