Skip to Content
MilliporeSigma
All Photos(1)

Documents

546674

Sigma-Aldrich

Copper(II) phthalocyanine

sublimed grade, Dye content 99 %

Synonym(s):

CuPc, Phthalocyanine blue, Pigment Blue 15

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C32H16CuN8
CAS Number:
147-14-8
Molecular Weight:
576.07
Colour Index Number:
74160
Beilstein/REAXYS Number:
4121848
EC Number:
205-685-1
MDL number:
MFCD00010719
UNSPSC Code:
12352103
PubChem Substance ID:
24878913
NACRES:
NA.23

grade

sublimed grade

composition

Dye content, 99%

λmax

678 nm

fluorescence

λem 404 nm

orbital energy

HOMO 5.2 eV 
LUMO 3.5 eV 

OLED device performance

ITO/CuPc/NPD/Alq3/C60/Mg:Ag

  • Color: green
  • Max. Luminance: 17200 Cd/m2

ITO/CuPc/NPD/Alq3/LiF/Al
  • Color: red
  • Max. Luminance: 2000 Cd/m2
  • Turn-On Voltage: 7.5 V

ITO/CuPc/NPD/CBP:FIrpic (6%)/BAlq3/LiF/Al
  • Color: blue
  • Max. EQE: 4.5 %

OPV device performance

ITO/CuPc/PTCDA/In

  • Short-circuit current density (Jsc): 53.1 mA/cm2
  • Open-circuit voltage (Voc): 0.57 V
  • Fill Factor (FF): 0.61
  • Power Conversion Efficiency (PCE): 4.2 %

ITO/PEDOT:PSS/CuPc/C60/BCP/Al
  • Short-circuit current density (Jsc): 18.8 mA/cm2
  • Open-circuit voltage (Voc): 0.58 V
  • Fill Factor (FF): 0.52
  • Power Conversion Efficiency (PCE): 3.6 %

SMILES string

c1ccc2c(c1)C3=NC4=[N@@H]5C(=Nc6n7c(N=C8c9ccccc9C%10=[N@@H]8[Cu]57N3C2=N%10)c%11ccccc6%11)c%12ccccc4%12

InChI

1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChI key

XCJYREBRNVKWGJ-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10-4 cm2/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.
TGA/DSC Lot specific traces available upon request

application

CuPc is a semiconducting material that can be used in a variety of optoelectronic devices such as light emitting diodes (LEDs), field effect transistors (FETs) and solar cells/organic photovoltaics (OPVs).

Storage Class

11 - Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

A facile molecularly engineered copper (II) phthalocyanine as hole transport material for planar perovskite solar cells with enhanced performance and stability
Yang G, et al.
Nano Energy, 31(1), 322-330 (2017)
Effects of substrate temperature on copper (II) phthalocyanine thin films
Jungyoon E, et al.
Applied Surface Science, 205(1-4), 274-279 (2003)
Single-crystal field-effect transistors based on copper phthalocyanine
Zeis R, et al.
Applied Physics Letters, 86(2), 022103-022103 (2005)
Very-high-efficiency double-heterostructure copper phthalocyanine/C 60 photovoltaic cells
Peumans P and Forrest SR
Applied Physics Letters, 79(1), 126-128 (2001)
Organic light-emitting diodes with improved hole-electron balance by using copper phthalocyanine/aromatic diamine multiple quantum wells
Qiu Y, et al.
Applied Physics Letters, 80(15), 2628-2630 (2002)
View All Related Papers

Articles

Metal-Organic Complexes for Doping

Highly reducing or oxidizing species enhance organic semiconductor conductivity by reducing charge-carrier injection barriers.

Plexcore® OC Hole Injection Inks

Plexcore® organic conductive inks are electronic grade inks formulated for use in the hole injection layers of OLEDs.

High-Purity Sublimed Materials for Organic Electronic Devices

Sublimed materials for organic electronic devices such of OFETs and OTFTs allow the achievement of better electronic properties, and may help increase a device’s lifetime.

Organic & Hybrid Electronics for Optical Analysis

Professor Shinar highlights low-cost, disposable sensor configurations in organic and hybrid electronics for healthcare applications.

See All

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service