396729

(2S,5S)-2,5-Hexanediol

99%, optical purity ee: 99% (GLC)

• Linear Formula: CH₃CH(OH)CH₂CH₂CH(OH)CH₃
• CAS Number: 34338-96-0
• Molecular Weight: 118.17
• Beilstein/REAXYS Number: 4652444
• MDL number: MFCD00082583
• UNSPSC Code: 12352001
• PubChem Substance ID: 24864681

Properties

• assay: 99%
• optical activity: [α]20/D +34.5°, c = 9 in chloroform
• optical purity: ee: 99% (GLC)
• bp: 212-215 °C (lit.)
• mp: 50-53 °C (lit.)
• SMILES string: C[C@H](O)CC[C@H](C)O
• InChI: 1S/C6H14O2/c1-5(7)3-4-6(2)8/h5-8H,3-4H2,1-2H3/t5-,6-/m0/s1
• InChI key: OHMBHFSEKCCCBW-WDSKDSINSA-N

Description

Application

Used in the synthesis of phospholanes. A building block in the synthesis of trans-2,5-dimethylpyrrolidine. C₂ symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302,H315,H319,H335
• pcodes: P261 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: 215.6 °F - closed cup
• flash_point_c: 102 °C - closed cup
• ppe: dust mask type N95 (US), Eyeshields, Gloves