340367

(1R)-(−)-Nopol

98%

• Synonym(s): (−)-Nopol, (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol, 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol
• Empirical Formula (Hill Notation): C₁₁H₁₈O
• CAS Number: 35836-73-8
• Molecular Weight: 166.26
• Beilstein/REAXYS Number: 3196379
• EC Number: 252-744-2
• MDL number: MFCD00075187
• UNSPSC Code: 12352002
• PubChem Substance ID: 24860803
• NACRES: NA.22

Properties

• assay: 98%
• form: viscous liquid
• optical activity: [α]24/D −37°, neat
• refractive index: n20/D 1.493 (lit.)
• bp: 230-240 °C (lit.)
• density: 0.973 g/mL at 25 °C (lit.)
• SMILES string: CC1(C)[C@H]2CC=C(CCO)[C@@H]1C2
• InChI: 1S/C11H18O/c1-11(2)9-4-3-8(5-6-12)10(11)7-9/h3,9-10,12H,4-7H2,1-2H3/t9-,10-/m0/s1
• InChI key: ROKSAUSPJGWCSM-UWVGGRQHSA-N

Description

General description

(1R)-(-)-Nopol is a chiral terpenol derivative.

Application

(1R)-(-)-Nopol may be used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids by reacting with tetraphosphorus decasulfide and 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides, respectively. It may also react with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302,H315,H319,H335
• pcodes: P261 - P264 - P271 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 208.4 °F - closed cup
• flash_point_c: 98 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter