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26253

Sigma-Aldrich

(3-Chloropropyl)trimethylsilane

≥97.0%

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About This Item

Empirical Formula (Hill Notation):
C6H15ClSi
CAS Number:
2344-83-4
Molecular Weight:
150.72
Beilstein/REAXYS Number:
1732625
EC Number:
219-059-0
MDL number:
MFCD00045299
UNSPSC Code:
12352100
PubChem Substance ID:
57648158
NACRES:
NA.22

assay

≥97.0%

refractive index

n20/D 1.431

bp

151 °C (lit.)

density

0.878 g/mL at 20 °C (lit.)

SMILES string

C[Si](C)(C)CCCCl

InChI

1S/C6H15ClSi/c1-8(2,3)6-4-5-7/h4-6H2,1-3H3

InChI key

QXDDDCNYAAJLBT-UHFFFAOYSA-N

Application

(3-Chloropropyl)trimethylsilane has been used in the preparation of:
  • 8-(3-trimethylsilylpropoxy)quinolone under phase transfer catalytic conditions
  • 5-trimethylsilyl pentanol
  • N-(tri-methylsilylalkyl)diamines

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

120.2 °F - closed cup

flash_point_c

49 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

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New deoxynojirimycin derivatives as potent inhibitors of intestinal a-glucohydrolases.
Lesur B, et al.
Bioorganic & Medicinal Chemistry Letters, 7(3), 355-360 (1997)
Silyl Modification of Biologically Active Compounds. 10. Lipid Type Organosilicon Derivatives of 8-Hydroxyquinoline and N-(2-Hydroxyethyl)-1, 2, 3, 4-tetrahydro (sila, iso) quinolines.
Segal I, et al.
Chemistry of Heterocyclic Compounds, 41(5), 613-624 (2005)
Organosilicon Compounds. Part V. Synthesis of N-(trimethylsilylalkyl) diamines and N-(trimethylsilylalkyl)-N'-(2-mercaptoethyl) diamines.
Thames SF and Edwards LH.
J. Chem. Soc. Sect. C, 2339-2342 (1968)

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