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259071

Sigma-Aldrich

5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride

≥94% (HPLC)

Synonym(s):

meso-Tetraphenylporphyrin iron(III) chloride

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About This Item

Empirical Formula (Hill Notation):
C44H28ClFeN4
CAS Number:
16456-81-8
Molecular Weight:
704.02
MDL number:
MFCD00012152
UNSPSC Code:
12352103
PubChem Substance ID:
24855684
NACRES:
NA.23

assay

≥94% (HPLC)

λmax

418 nm

SMILES string

Cl[Fe]1n2c3ccc2c(-c4ccccc4)c5ccc(n5)c(-c6ccccc6)c7ccc(c(-c8ccccc8)c9ccc(n9)c3-c%10ccccc%10)n17

InChI

1S/C44H28N4.ClH.Fe/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;

InChI key

ZDYSAMCSFRQDMN-YKKPBKTHSA-M

Application

  • Carbon Nanopowder-Based Stochastic Sensor: This research describes the application of iron(III) porphyrin in carbon nanopowder-based sensors for the ultrasensitive assay of biomarkers in whole blood (Stefan-van Staden et al., 2022).
  • High sensitivity carbon monoxide detector: Discusses the development of a carbon monoxide detector using iron tetraphenyl porphyrin functionalized reduced graphene oxide (Shirsat et al., 2023).
  • Sulfur-Doped Graphene-Based Electrochemical Sensors: This article examines the use of iron tetraphenyl porphyrin in sensors for detecting limonene in beverages (Niculae et al., 2022).

Features and Benefits

Effective catalyst for the silylation of hydroxyl groups with hexamethyldisilazane at room temperature.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificates of Analysis (COA)

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W R Scheidt et al.
Acta crystallographica. Section C, Crystal structure communications, 45 ( Pt 8), 1214-1216 (1989-08-15)
[FeCl(C44H28N4)], Mr = 704.03, monoclinic, P21/n, a = 10.254 (2), b = 15.969 (3), c = 20.810 (4) A, beta = 90.48 (2) degree, V = 3407.7 A3, Z = 4, Dx = 1.37 g cm-3, Mo K alpha, lambda
K Tajima et al.
Biochemical and biophysical research communications, 166(2), 924-930 (1990-01-30)
Coordination reaction between linolenic-acid-hydroperoxide (LHPO) and chloro(5, 10, 15, 20-tetraphenyl)-porphyrinato iron (III), Fe(III)TPPCl, was investigated by means of ESR. ESR spectra of the ferric low-spin complex (g1 = 2.336, g2 = 2.174 and g3 = 1.929) was recorded for the

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