682527

6-(Ferrocenyl)hexanethiol

• Synonym(s): FHT, 6-(Mercaptohexyl)ferrocene
• Empirical Formula (Hill Notation): C₁₆H₂₂FeS
• CAS Number: 134029-92-8
• Molecular Weight: 302.26
• MDL number: MFCD09265168
• UNSPSC Code: 12352103
• PubChem Substance ID: 24885720
• NACRES: NA.23

Properties

• bp: 321-353 °C
• SMILES string: [Fe].[CH]1[CH][CH][CH][CH]1.SCCCCCC[C]2[CH][CH][CH][CH]2
• InChI: 1S/C11H17S.C5H5.Fe/c12-10-6-2-1-3-7-11-8-4-5-9-11;1-2-4-5-3-1;/h4-5,8-9,12H,1-3,6-7,10H2;1-5H;
• InChI key: YENJERDZPAXYRX-UHFFFAOYSA-N

Description

General description

6-(Ferrocenyl)hexanethiol (FHT) is a ferrocenyl alkanethiol that forms a self-assembled monolayer (SAM) where ferrocenyl linkages can facilitate the electron exchange between the coating and the substrate.

Application

FHT can be used as a SAM on gold substrates to act as an electron transport medium which can be potentially used in bio-electrochemical devices. FHT may also be used to functionalize graphene coated gold surfaces by forming gold-thiol linkages which can be used as electron transfer mediators.

Monolayers of this material are easy to fabricate and provide a stable and reproducible system and are used to detect molecular interactions.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter