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279811

Sigma-Aldrich

Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate

98%

Synonym(s):

Cobaltocenium hexafluorophosphate

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About This Item

Empirical Formula (Hill Notation):
C10H10CoF6P
CAS Number:
12427-42-8
Molecular Weight:
334.08
EC Number:
235-655-3
MDL number:
MFCD00011874
UNSPSC Code:
12161600
PubChem Substance ID:
24856910
NACRES:
NA.22

assay

98%

reaction suitability

core: cobalt
reagent type: catalyst

SMILES string

[Co+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F

InChI

1S/2C5H5.Co.F6P/c2*1-2-4-5-3-1;;1-7(2,3,4,5)6/h2*1-5H;;/q;;+1;-1

InChI key

IASMSXQWVNBFOM-UHFFFAOYSA-N

Application

Uses:
  • Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
  • Reactant for modification of organometallic electrodes surfaces through cathodic reduction
  • Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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