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Sigma-Aldrich

Copper(II) perchlorate hexahydrate

98%

Synonym(s):

Cupric perchlorate hexahydrate

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About This Item

Linear Formula:
Cu(ClO4)2 · 6H2O
CAS Number:
10294-46-9
Molecular Weight:
370.54
EC Number:
237-391-4
MDL number:
MFCD00149666
UNSPSC Code:
12352302
PubChem Substance ID:
24852890
NACRES:
NA.23

assay

98%

form

crystalline

reaction suitability

reagent type: oxidant

density

2.225 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

O.O.O.O.O.O.[Cu++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.Cu.6H2O/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);;6*1H2/q;;+2;;;;;;/p-2

InChI key

NHELIHXBJRANPL-UHFFFAOYSA-L

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General description

The monoclinic structure of copper perchlorate hexahydrate was analyzed by X-ray diffraction. The product may be used as a catalyst during the reaction of 5-methylisophthalaldehyde with 1,3-diaminopropane. Benzaldehyde semicarbazones, reacted with copper perchlorate hexahydrate in acetonitrile, may yield corresponding 1,2,4-triazolin-5-ones.

Application

  • Methanol[1-(methoxymethanimidoyl)-2-(pyridin-2-ylmethyl)guanidine]bis(perchlorato)copper(II).: This study reports the synthesis and crystal structure of a new copper(II) complex with potential applications in materials science and catalysis. The research focuses on the structural characterization of the complex, which is crucial for understanding its reactivity and potential uses in various chemical processes (Meenongwa et al., 2012).
  • Oxidative cleavage of DNA by a dipyridoquinoxaline copper(II) complex in the presence of ascorbic acid.: This research explores the catalytic activity of a copper(II) complex in oxidative DNA cleavage. The findings demonstrate the complex′s potential application in biochemical studies and the development of new catalytic processes for DNA manipulation and analysis (Santra et al., 2002).

pictograms

Flame over circleExclamation mark
GHS03,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Sze-Wing Ng et al.
Molecules (Basel, Switzerland), 25(9) (2020-05-01)
A new tetradentate mixed aza-thioether macrocyclic ligand 2,6-dithia[7](2,9)-1,10-phenanthrolinophane ([13]ane(phenN2)S2) was successfully synthesized. Reacting metal precursors [Fe(CH3CN)2(OTf)2], Ni(ClO4)2·6H2O, and Cu(ClO4)2·6H2O with one equivalent of [13]ane(phenN2)S2 afforded [Fe([13]ane(phenN2)S2)(OTf)2] (1), [Ni([13]ane(phenN2)S2)](ClO4)2 (2(ClO4)2), and [Cu([13]ane(phenN2)S2)(OH2)](ClO4)2 (3(ClO4)2), respectively. The structures of [13]ane(phenN2)S2 and all of
Sabri Ahmed Cherrak et al.
PloS one, 11(10), e0165575-e0165575 (2016-10-28)
Natural flavonoids such as quercetin, (+)catechin and rutin as well as four methoxylated derivatives of quercetin used as models were investigated to elucidate their impact on the oxidant and antioxidant status of human red blood cells (RBCs). The impact of
Complexes of binucleating ligands. III. Novel complexes of a macrocyclic binucleating ligand.
Pilkington NH and Robson R
Australian Journal of Chemistry, 23(11), 2225-2236 (1970)
A study of the mechanism of the oxidative cyclization of benzaldehyde semicarbazones induced by cupric perchlorate in acetonitrile
Noto R, et al.
Journal of Heterocyclic Chemistry, 32(4), 1277-1282 (1995)
The crystal structure of copper perchlorate hexahydrate, Cu (ClO4) 2? 6 H20.
Mani NV and Ramaseshan S
Zeitschrift fur Kristallographie, 115(1-6), 97-109 (1961)
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