124133

3-Bromoquinoline

98%

• Empirical Formula (Hill Notation): C₉H₆BrN
• CAS Number: 5332-24-1
• Molecular Weight: 208.05
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 24847599
• EC Number: 226-237-1
• Beilstein/REAXYS Number: 112939
• MDL number: MFCD00006767
• Assay: 98%
• Form: liquid

Properties

• Quality Segment: 100
• assay: 98%
• form: liquid
• refractive index: n20/D 1.664 (lit.)
• bp: 274-276 °C (lit.)
• mp: 13-15 °C (lit.)
• density: 1.533 g/mL at 25 °C (lit.)
• functional group: bromo
• SMILES string: Brc1cnc2ccccc2c1
• InChI: 1S/C9H6BrN/c10-8-5-7-3-1-2-4-9(7)11-6-8/h1-6H
• InChI key: ZGIKWINFUGEQEO-UHFFFAOYSA-N

Description

General description

3-Bromoquinoline undergoes bromine-magnesium exchange reaction with lithium tributylmagnesate in toluene at -10°C, which is quenched by various electrophiles to yield functionalized quinolines.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319
• pcodes: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Storage Class: 10 - Combustible liquids
• wgk: WGK 3
• flash_point_f: 230.0 °F - closed cup
• flash_point_c: 110 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter