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Key Documents

211710

Sigma-Aldrich

Trimethylgermanium bromide

98%

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About This Item

Linear Formula:
(CH3)3GeBr
CAS Number:
Molecular Weight:
197.65
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

refractive index

n20/D 1.47 (lit.)

bp

114 °C (lit.)

mp

−25 °C (lit.)

density

1.54 g/mL at 25 °C (lit.)

SMILES string

C[Ge](C)(C)Br

InChI

1S/C3H9BrGe/c1-5(2,3)4/h1-3H3

InChI key

WMFCXPWEKRAKMH-UHFFFAOYSA-N

Application

Reagent for the formation of dienolates of α,β-unsaturated esters. Also useful for methylenecyclopentane annulation reactions.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

98.6 °F - closed cup

Flash Point(C)

37 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The Journal of Organic Chemistry, 55, 3454-3454 (1990)
Journal of Organometallic Chemistry, 373, 143-143 (1989)

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