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Merck
  • Chiral porphyrin dimer with a macrocyclic cavity for intercalation of aromatic guests.

Chiral porphyrin dimer with a macrocyclic cavity for intercalation of aromatic guests.

Chemical communications (Cambridge, England) (2011-04-13)
Tadashi Ema, Norichika Ura, Katsuya Eguchi, Yuhei Ise, Takashi Sakai
摘要

Chiral diporphyrin receptor 1, which has a macrocyclic cavity to sandwich aromatic guest molecules via double π-π stacking interactions, enabled the naked-eye detection of an aromatic explosive as well as chiral discrimination in NMR.