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937401

Sigma-Aldrich

(tBuXPhos)Pd(p-TMSCH2CH2CO2C6H4)(Br)

≥95%

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About This Item

經驗公式(希爾表示法):
C41H62BrO2PPdSi
CAS號碼:
分子量::
832.31
分類程式碼代碼:
12352142
NACRES:
NA.21

品質等級

化驗

≥95%

形狀

powder or crystals

反應適用性

reaction type: Cross Couplings

顏色

white to faint yellow

官能基

(Palladium)
phosphine

儲存溫度

room temp

SMILES 字串

Br[Pd](C1=CC=C(C(OCC[Si](C)(C)C)=O)C=C1)[P](C2=CC=CC=C2C3=C(C(C)C)C=C(C(C)C)C=C3C(C)C)(C(C)(C)C)C(C)(C)C

一般說明

(tBuXPhos)Pd(p-TMSCH2CH2CO2C6H4)(Br) is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Ryan P King et al.
Organic letters, 23(20), 7927-7932 (2021-10-07)
The utilization of isolated Palladium Oxidative Addition Complexes (OACs) has had a significant impact on Pd-catalyzed and Pd-mediated cross-coupling reactions. Despite their importance, widespread utility of OACs has been limited by the instability of their precursor complexes. Herein, we report

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