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Merck
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文件

378135

Sigma-Aldrich

powder, −325 mesh, ≥99%

同義詞:

Glucinium

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About This Item

經驗公式(希爾表示法):
Be
CAS號碼:
分子量::
9.01
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:

化驗

≥99%

形狀

powder

自燃溫度

1198 °F

反應適用性

reagent type: Lewis acid
core: beryllium

reagent type: catalyst

電阻係數

4.46 μΩ-cm, 20°C

粒徑

−325 mesh

bp

2970 °C (lit.)

mp

1278 °C (lit.)

密度

1.85 g/mL at 25 °C (lit.)

SMILES 字串

[Be]

InChI

1S/Be

InChI 密鑰

ATBAMAFKBVZNFJ-UHFFFAOYSA-N

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應用

Starting material for novel sterically encumbered arylberyllium compounds.

Reagent for synthesis of:
  • Beryllium phthalocyanine and its derivatives
  • Catalyst with cerium oxide for oxidative coupling of methane
  • Organoberyllium compounds

Reagent for:
  • Metal mediated dechlorination
  • Stereoselective Horner-Wadsworth-Emmons reactions

象形圖

Skull and crossbonesHealth hazard

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Carc. 1B Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


分析證明 (COA)

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The use of the terphenyl substituent -C(6)H(3)-2,6-Mes(2) (abbreviated Ar) has permitted the synthesis of several new low-coordinate beryllium compounds. Reaction of 1 equiv of LiAr with BeCl(2)(OEt(2))(2) or BeBr(2)(OEt(2))(2) (1) gives the monomeric complexes ArBeX(OEt(2)) (X = Cl (2); Br

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