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278742

Sigma-Aldrich

(1S,2R,5S)-(+)-薄荷醇 (R)-对甲苯亚磺酸酯

98%

同義詞:

(R)-(+)-薄荷基 对甲苯亚磺酸酯

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About This Item

經驗公式（希爾表示法）:
C17H26O2S
CAS號碼:
91796-57-5
分子量：:
294.45
分類程式碼代碼:
12352000
PubChem物質ID:
24856827
NACRES:
NA.22

化驗

98%

形狀

solid

光學活性

[α]20/D +200°, c = 2 in acetone

mp

104-106 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

C[C@H]1CC[C@H](C(C)C)[C@H](C1)OS(=O)c2ccc(C)cc2

InChI

1S/C17H26O2S/c1-12(2)16-10-7-14(4)11-17(16)19-20(18)15-8-5-13(3)6-9-15/h5-6,8-9,12,14,16-17H,7,10-11H2,1-4H3/t14-,16+,17-,20+/m0/s1

InChI 密鑰

NQICGNSARVCSGJ-DZIWXPPMSA-N

應用

(1S,2R,5S)-(+)-Menthyl (R)-p-toluenesulfinate can be used:
  • As a chiral electrophile in the synthesis of fluorescent triazolopyridine ligands.
  • To prepare various sulfinimines, which are further used in the synthesis of α-aminophosphonic acids by reacting with borane complexes.
  • In one of the key synthetic steps for the synthesis of (S)-(+)-ethyl β-amino-3-pyridinepropanoate, a component of an antiplatelet agent.

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

分析證明 (COA)

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Triazolopyridines. Part 25: Synthesis of new chiral ligands from [1, 2, 3] triazolo [1, 5-a] pyridines
Abarca B, et al.
Tetrahedron, 63(42), 10479-10485 (2007)
A new efficient procedure for asymmetric synthesis of alpha-aminophosphonic acids via addition of lithiated bis (diethylamino) phosphine borane complex to enantiopure sulfinimines
Mikolajczyk M, et al.
Tetrahedron Asymmetry, 13(23), 2571-2576 (2002)
An Efficient Synthesis of (S)-(+)-Ethyl beta-Amino-3-pyridinepropanoate Using Enantiopure Sulfinimines
Davis FA, et al.
The Journal of Organic Chemistry, 61(6), 2222-2225 (1996)

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