推薦產品
化驗
97%
形狀
solid
mp
98-100 °C (lit.)
SMILES 字串
CC(=O)Oc1ccc(OC(C)=O)c(OC(C)=O)c1
InChI
1S/C12H12O6/c1-7(13)16-10-4-5-11(17-8(2)14)12(6-10)18-9(3)15/h4-6H,1-3H3
InChI 密鑰
AESFGSJWSUZRGW-UHFFFAOYSA-N
應用
1,2,4-Triacetoxybenzene can be used as a starting material:
- To prepare aminated hydroxynaphthazarins, echinamines A and B.
- To synthesize 6,7-dihydroxychromenones, which are further used to prepare various crown ethers.
- In the total synthesis of natural product santalin Y.
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號,寫有 ‘Lot’或‘Batch’.。
Synthesis of Echinamines A and B, the First Aminated Hydroxynaphthazarins Produced by the Sea Urchin Scaphechinus m irabilis and Its Analogues
Journal of Natural Products, 69, 1125-1129 (2006)
The synthesis of novel crown ethers, part ix, 3-phenyl chromenone-crown ethers
Journal of Heterocyclic Chemistry, 38, 1291-1295 (2001)
Journal of natural products, 69(8), 1125-1129 (2006-08-29)
The first total synthesis of two marine aminated hydroxynaphthazarins, echinamines A (3-amino-7-ethyl-2,5,6,8-tetrahydroxy-1,4-naphthoquinone) and B (2-amino-7-ethyl-3,5,6,8-tetrahydroxy-1,4-naphthoquinone), produced by the sea urchin Scaphechinus mirabilis is described. This was achieved from 1,2,4-triacetoxybenzene (13) through a sequence involving double Fries rearrangement of 13, reduction
Biomimetic total synthesis of santalin Y
Angewandte Chemie (International Edition in English), 54, 5079-5083 (2015)
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