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683167

Sigma-Aldrich

Chiralyst P461

Umicore

Synonym(s):

Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer, Di(μ-chloro)bis(norbornadiene)dirhodium(I), 2,5-Norbornadiene-rhodium(I) chloride dimer, Chloro(2,5-norbornadiene)rhodium(I) dimer, Rhodium(I) chloride 2,5-Norbornadiene complex dimer, [Rh(nbd)Cl]2

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About This Item

Empirical Formula (Hill Notation):
C14H16Cl2Rh2
CAS Number:
12257-42-0
Molecular Weight:
460.99
EC Number:
235-510-4
MDL number:
MFCD00198060
UNSPSC Code:
12161600
PubChem Substance ID:
329760800
NACRES:
NA.22

form

powder

reaction suitability

core: rhodium
reagent type: catalyst

SMILES string

Cl[Rh].Cl[Rh].[CH]1[CH]C2[CH][CH]C1C2.[CH]3[CH]C4[CH][CH]C3C4

InChI

1S/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2/t2*6-,7+;;;;

InChI key

RXDWVIOULPVOEO-SEGRDSFWSA-L

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Related Categories

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Hydrosilylation Catalysts
Catalyst for valence isomerization and N-heterocyclization; incombination with phosphorus ligands are catalysts for hydrogenationof many functional groups and hydroformylation; withchiral ligands are catalysts for asymmetric hydrogenation

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Watanabe, Y.; Shim, S. C.; Mitsudo, T.
Bulletin of the Chemical Society of Japan, 54, 3460-3460 (1981)
Taylor, R. B.; Jennings, P. W.
Inorganic Chemistry, 20, 3997-3997 (1981)
Becalski, A. G.; Cullen,W. R. et al.
Inorganic Chemistry, 30, 5002-5002 (1991)
Tani, K.; Tanigawa, E.; Tatsuno, Y.; Otsuka, S.
Journal of Organometallic Chemistry, 279, 87-87 (1985)

Articles

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

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