New mixed alkaline-earth nitridomolybdate(VI) nitride oxides with anion-ordered sub-structures.

New mixed alkaline-earth nitridomolybdate(VI) nitride oxides with anion-ordered sub-structures.

Dalton transactions (Cambridge, England : 2003) (2004-07-15)

Charles F Baker, Marten G Barker, Claire Wilson, Duncan H Gregory

ABSTRACT

New molybdenum(VI) nitride oxides were synthesised by the reaction of strontium nitride and calcium nitride with molybdenum foil at high temperature in sealed stainless steel crucibles. The reactions yielded single crystalline products determined by X-ray diffraction to form complex structures in the triclinic space group P1(no. 2). The mixed alkaline earth compounds with composition Ca38Sr13[MoN4]12N8O3 and Ca36Sr15[MoN4]12N8O3 are isostructural with the quaternary nitride oxides Sr51[WN4]12N8O3 and Ca51[WN4]12N8O3. The structures contain isolated [MoN4](6-) tetrahedra, partially disordered alkaline earth cations and an ordered sublattice of N(3-) and O(2-) anions. Oxide anions are coordinated only to the alkaline earth metals. The title compounds are the first mixed alkaline earth metal nitride oxides.

MATERIALS

Product Number

Brand

Product Description

GF46843645

Molybdenum, foil, light tested, 50x50mm, thickness 0.009mm, 99.9%

GF68872078

Molybdenum, foil, 4mm disks, thickness 0.020mm, annealed, 99.9%

GF87314474

Molybdenum, foil, 25mm disks, thickness 0.15mm, annealed, 99.9%

GF82331265

Molybdenum, foil, light tested, 25x25mm, thickness 0.05mm, annealed, 99.9%

GF83341111

Molybdenum, foil, not light tested, 25x25mm, thickness 0.005mm, 99.9%

GF77151629

Molybdenum, foil, 8mm disks, thickness 0.025mm, annealed, 99.9%

GF15667229

Molybdenum, foil, light tested, 100x100mm, thickness 0.01mm, 99.9%

GF76305270

Molybdenum, foil, 8mm disks, thickness 0.015mm, as rolled, 99.9%

GF46109099

Molybdenum, foil, 8mm disks, thickness 0.03mm, annealed, 99.9%

GF17537812

Molybdenum, foil, 8mm disks, thickness 0.007mm, 99.9%

GF83172809

Molybdenum, foil, light tested, 130x130mm, thickness 0.015mm, as rolled, 99.9%

GF94586372

Molybdenum, foil, 8mm disks, thickness 0.005mm, 99.9%

GF04498702

Molybdenum, foil, 8mm disks, thickness 0.0125mm, 99.9%

GF87443477

Molybdenum, foil, 8mm disks, thickness 0.075mm, annealed, 99.9%

GF48963549

Molybdenum, foil, light tested, 50x50mm, thickness 0.006mm, 99.9%

GF41758768

Molybdenum, foil, not light tested, 50x50mm, thickness 0.009mm, 99.9%

GF66431606

Molybdenum, foil, not light tested, 25x25mm, thickness 0.006mm, 99.9%

GF20045786

Molybdenum, foil, not light tested, 50x50mm, thickness 0.002mm, 99.9%

GF84555681

Molybdenum, foil, light tested, 150x150mm, thickness 0.05mm, annealed, 99.9%

GF04296618

Molybdenum, foil, light tested, 50x50mm, thickness 0.075mm, annealed, 99.9%

GF87175930

Molybdenum, foil, 100x100mm, thickness 0.20mm, annealed, 99.9%

GF16892242

Molybdenum, foil, light tested, 25x25mm, thickness 0.004mm, 99.9%

GF37145358

Molybdenum, foil, not light tested, 50x50mm, thickness 0.007mm, 99.9%

GF75912914

Molybdenum, foil, light tested, 50x50mm, thickness 0.008mm, 99.9%

GF62927297

Molybdenum, foil, 100x100mm, thickness 0.25mm, annealed, polished on both sides, 99.9%

GF91334213

Molybdenum, foil, 100x100mm, thickness 2.0mm, annealed, 99.9%

GF60831671

Molybdenum, foil, 150x150mm, thickness 0.125mm, annealed, 99.9%

GF90528699

Molybdenum, foil, 150x150mm, thickness 0.15mm, annealed, 99.9%

GF65357523

Molybdenum, foil, 100x100mm, thickness 0.25mm, annealed, 99.9%

GF58061280

Molybdenum, foil, 100x100mm, thickness 0.75mm, annealed, 99.9%