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  • An octacobalt cluster based, (3,12)-connected, magnetic, porous coordination polymer.

An octacobalt cluster based, (3,12)-connected, magnetic, porous coordination polymer.

Chemical communications (Cambridge, England) (2010-08-03)
Lei Hou, Wei-Xiong Zhang, Jie-Peng Zhang, Wei Xue, Yue-Biao Zhang, Xiao-Ming Chen
ABSTRACT

Solvothermal reaction of CoSO(4) with 2,6-di-p-carboxyphenyl-4,4'-bipyridine affords a novel, octacobalt cluster based, (3,12)-connected porous framework, which exhibits gas sorption and spin-glassy magnetic behaviour.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Cobalt(II) sulfate heptahydrate, ReagentPlus®, ≥99%