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560170

Sigma-Aldrich

2-Bromo-4-methylbenzoic acid

97%

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About This Item

Linear Formula:
Br(CH3)C6H3COOH
CAS Number:
7697-27-0
Molecular Weight:
215.04
MDL number:
MFCD00045797
UNSPSC Code:
12352100
PubChem Substance ID:
24879850
NACRES:
NA.22

Assay

97%

form

solid

mp

143-147 °C (lit.)

SMILES string

Cc1ccc(C(O)=O)c(Br)c1

InChI

1S/C8H7BrO2/c1-5-2-3-6(8(10)11)7(9)4-5/h2-4H,1H3,(H,10,11)

InChI key

ZZYYOHPHSYCHQG-UHFFFAOYSA-N

General description

2-Bromo-4-methylbenzoic acid can be prepared from 2-bromo-4-methylbenzonitrile via hydrolysis.

Application

2-Bromo-4-methylbenzoic acid may be used to synthesize:
  • 4′-hydroxy-5:6′-dimethyldibenzo-α-pyrone
  • 2-bromo-4-methylbenzophenone
  • 7-hydroxy-5′-methyl-6-n-hexyl-3:4-benzocoumarin
  • 2-(trimethylsilyl)ethyl 2-bromo-4-methylbenzoate

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Intramolecular Reactions. IV. Chain Transfer Reaction Involving an Aromatic Hydrogen Atom and Related Reactions of 2-(4'-Methylbenzoyl)-benzenediazonium Salts1.
DeTar DF and Relyea DI.
Journal of the American Chemical Society, 78(17), 4302-4305 (1955)
Studies in the biochemistry of micro-organisms. 90. Alternariol and alternariol monomethyl ether, metabolic products of Alternaria tenuis.
Raistrick H, et al.
The Biochemical Journal, 55(3), 421-421 (1953)
204. Tetrahydrodibenzopyran derivatives isomeric with tetrahydrocannabinols.
Avison AWD, et al.
Journal of the Chemical Society, 952-955 (1949)
A Radioiodinated MIBG-octreotate conjugate exhibiting enhanced uptake and retention in sstr2-expressing tumor cells.
Vaidyanathan G, et al.
Bioconjugate Chemistry, 18(6), 2122-2130 (2007)

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