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403016

Sigma-Aldrich

Sodium chlorate

ACS reagent, ≥99.0%

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About This Item

Linear Formula:
NaClO3
CAS Number:
Molecular Weight:
106.44
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent

Agency

suitable for EPA 300

Assay

≥99.0%

form

powder or crystals

impurities

≤0.001% N compounds
≤0.005% insolubles

mp

248-261 °C (lit.)

solubility

water: soluble

anion traces

bromate (BrO3-): ≤0.015%
chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.001%

cation traces

Ca: ≤0.005%
Fe: ≤5 ppm
K: ≤0.01%
Mg: ≤0.002%
heavy metals (as Pb): ≤0.001%

SMILES string

[Na+].[O-]Cl(=O)=O

InChI

1S/ClHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1

InChI key

YZHUMGUJCQRKBT-UHFFFAOYSA-M

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General description

Sodium chlorate is a hygroscopic, achiral ionic compound which on crystallization forms two enantiomeric chiral crystals. It is reported to be a probable byproduct of the drinking water disinfectant, chlorine dioxide (ClO2). d-sodium chlorate may be utilized as chiral initiators in the synthesis of (S)-5-pyrimidyl alkanols. Commercial production of sodium chlorate is by anodic oxidation of NaCl. It finds application as herbicide, oxidizing agent and as a starting material in the synthesis of sodium perchlorate.

Application

Sodium chlorate may be used as an oxidizing agent to abstract zinc from sphalerite.

Biochem/physiol Actions

sulfation biosynthesis inhibitor

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Ox. Sol. 1

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Kinetics of sphalerite dissolution by sodium chlorate in hydrochloric acid.
Uca G.
Hydrometallurgy, 95(1), 39-43 (2009)
Highly enantioselective asymmetric autocatalysis induced by chiral ionic crystals of sodium chlorate and sodium bromate.
Sato I, et al.
J. Mol. Catal. A: Chem., 216(2), 209-214 (2004)
Subchronic sodium chlorate exposure in drinking water results in a concentration-dependent increase in rat thyroid follicular cell hyperplasia.
Hooth MJ, et al.
Toxicologic Pathology, 29(2), 250-259 (2001)
Eagleson M
Concise Encyclopedia Chemistry, 996-996 (1994)
Asymmetric synthesis of optically active sodium chlorate and bromate crystals.
Pagni RM and Compton RN.
Crystal Growth & Design, 2(4), 249-253 (2002)

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This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

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