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45395

Chlorpyrifos

PESTANAL®, analytical standard

Synonym(s):

Chlorpyriphos

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About This Item

Empirical Formula (Hill Notation):
C9H11Cl3NO3PS
CAS Number:
Molecular Weight:
350.59
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
220-864-4
Beilstein/REAXYS Number:
1545756
MDL number:
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grade

analytical standard

Quality Segment

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCOP(=S)(OCC)Oc1nc(Cl)c(Cl)cc1Cl

InChI

1S/C9H11Cl3NO3PS/c1-3-14-17(18,15-4-2)16-9-7(11)5-6(10)8(12)13-9/h5H,3-4H2,1-2H3

InChI key

SBPBAQFWLVIOKP-UHFFFAOYSA-N

General description

Chlorpyrifos belongs to the organophosphorus class of insecticides, effectively used for the control of a variety of insect pests such as mosquitoes, fire ants, cockroaches, horn flies, lice, fleas, turf and ornamental plant insects.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Chlorpyrifos may be used as an analytical reference standard for the quantification of the analyte in waste discharges and biological samples using different chromatography techniques.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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format

neat

format

neat

format

neat

format

neat

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

grade

analytical standard

grade

certified reference material, TraceCERT®

grade

analytical standard

grade

analytical standard

product line

PESTANAL®

product line

TraceCERT®

product line

PESTANAL®

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

shelf life

limited shelf life, expiry date on the label

shelf life

limited shelf life, expiry date on the label

shelf life

limited shelf life, expiry date on the label

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C


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pictograms

Skull and crossbonesEnvironment

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges



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Validation of UV Spectrophotometric and HPLC Methods for Quantitative determination of chlorpyrifos
Zalat.A.O, et al.
International Letters of Chemistry, Physics and Astronomy, 2, 58-63 (2014)
Eisler's Encyclopedia of Environmentally Hazardous Priority Chemicals (2007)
Liquid chromatography--tandem mass spectrometry method for the simultaneous quantitative determination of the organophosphorus pesticides dimethoate, fenthion, diazinon and chlorpyrifos in human blood
Salm P, et al.
Journal of Chromatography. B, Biomedical Sciences and Applications, 877(5-6), 568-574 (2009)



Global Trade Item Number

SKUGTIN
45395-100MG04061835352975

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Hello, what solvent is chlorpyrifos soluble in? can the solution be stored in single use aliquots in the freezer? Thank you

    1 answer
    1. The solubility and solution stability of this product have not been determined. However, other sources note that this material is soluble in water up to 100 mg/ml and DMSO(anhydrous) at 50 mg/mL. Sonication may be required for higher concentrations. Stock solutions may be stored for up to 6 months at -80°C and 1 month at -20°C. This information has not been validated.

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