936715

Grubbs Catalyst^® M300 ChemBeads

• Synonym(s): Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(II) ChemBeads, Grubbs Catalyst^® 3rd Generation ChemBeads, Grubbs Catalyst^® C884 ChemBeads, Grubbs Catalyst^® M37a (C884) ChemBeads, [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridine)ruthenium(II) ChemBeads, [1,3-Dimesityl-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridine)ruthenium(II) ChemBeads
• Empirical Formula (Hill Notation): C₃₈H₄₀Br₂Cl₂N₄Ru
• CAS Number: 900169-53-1
• Molecular Weight: 884.54
• UNSPSC Code: 12352300

Properties

• form: solid
• Quality Level: 100
• composition: loading of catalyst, 4-6 wt. %
• reaction suitability: reagent type: catalyst; core: ruthenium; reaction type: Ring-Opening Polymerization
• storage temp.: 2-8°C
• SMILES string: Brc1cccnc1.Brc2cccnc2.Cc3cc(C)c(N4CCN(C4=[Ru](Cl)(Cl)=Cc5ccccc5)c6c(C)cc(C)cc6C)c(C)c3
• InChI: 1S/C21H26N2.C7H6.2C5H4BrN.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-7-5-3-2-4-6-7;2*6-5-2-1-3-7-4-5;;;/h9-12H,7-8H2,1-6H3;1-6H;2*1-4H;2*1H;/q;;;;;;+2/p-2
• InChI key: YDOACSUCKSODBO-UHFFFAOYSA-L

Description

General description

ChemBeads glass beads coated with Grubbs Catalyst^® M300.

Application

Metathesis: Ruthenium-Based Metathesis Catalysts Labile pyridine ligands result in a very fast initiator (even at 0 °C). Effective in cross metathesis of acrylonitrile. Also effective in RCM and the ROMP production of block copolymers and polymers with narrow PDIs

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

For larger scale uses, product also available in powdered form (682330)

Other Notes

Grubbs Catalyst^® Technology for Olefin Metathesis by Aldrich



High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Legal Information

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Safety Information

• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable