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689327

Sigma-Aldrich

Titration solution for quantitative analysis of butyllithium

2-propanol solution in toluene with 0.2% 1,10-phenanthroline

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About This Item

Empirical Formula (Hill Notation):
C12H8N2
Molecular Weight:
180.21
UNSPSC Code:
12352103
Pricing and availability is not currently available.

form

liquid

shelf life

limited shelf life, expiry date on the label

composition

2-propanol, 1.0 M

impurities

≤0.04% water

Application

2-propanol solution in toluene with 0.2% 1,10-phenanthroline can be used as a titration solution to obtain the accurate concentration of the butyllithium reagent in the solution.[1]

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

41.0 °F

Flash Point(C)

5 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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?-and ??-Lithiation-Electrophile Trapping of N-Thiopivaloyl and N-tert-Butoxythiocarbonyl ?-Substituted Azetidines: Rationalization of the Regiodivergence Using NMR and Computation
Jackson KE, et al.
The Journal of Organic Chemistry, 80, 9838-9846 (2015)

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