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63796

Sigma-Aldrich

(3-Mercaptopropyl)methyldimethoxysilane

≥95.0%

Synonym(s):

Dimethoxy-(3-mercaptopropyl)methylsilane

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About This Item

Linear Formula:
CH3Si(OCH3)2CH2CH2CH2SH
CAS Number:
31001-77-1
Molecular Weight:
180.34
Beilstein:
2424867
EC Number:
250-426-8
MDL number:
MFCD00053923
UNSPSC Code:
12352103
PubChem Substance ID:
57651962
NACRES:
NA.22

Assay

≥95.0%

form

liquid

refractive index

n20/D 1.45 (lit.)
n20/D 1.450

bp

96 °C/30 mmHg (lit.)

density

1 g/mL at 25 °C (lit.)

SMILES string

CO[Si](C)(CCCS)OC

InChI

1S/C6H16O2SSi/c1-7-10(3,8-2)6-4-5-9/h9H,4-6H2,1-3H3

InChI key

IKYAJDOSWUATPI-UHFFFAOYSA-N

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Application

(3-Mercaptopropyl)methyldimethoxysilane (MPMDMS) can be used as a silane precursor in the synthesis of:
  • Nafion-MPMDMS nanocomposite membranes by sol-gel method.
  • MPMDMS functionalized magnetic- polysilsesquioxane (PSSQ) nanoparticles applicable for heavy metal ions adsorption.
  • Thiol-organosilica nanoparticles.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

199.4 °F - closed cup

Flash Point(C)

93 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Nafion-MPMDMS nanocomposite membranes with low methanol permeability.
Ladewig BP, et al.
Electrochemical Communications, 9(4), 781- 786 (2007)
One-pot synthesis and characterization of three kinds of thiol- organosilica nanoparticles.
Nakamura M and Ishimura K
Langmuir, 24(9), 5099- 5108 (2008)
One-pot synthesis of multi-functional magnetite- polysilsesquioxane hybrid nanoparticles for the selective Fe3+ and some heavy metal ions adsorption.
Nagappan S, et al.
Royal Society of Chemistry Advances, 7(31), 19106- 19116 (2017)
Pamela J Walsh et al.
Scientific reports, 7(1), 14138-14138 (2017-10-28)
Porous silica is an attractive biomaterial in many applications, including drug-delivery systems, bone-graft fillers and medical devices. The issue with porous silica biomaterials is the rate at which they resorb and the significant role played by interfacial chemistry on the
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