- (2-methoxyphenyl)dimethylsilyl lithium and cuprate reagents offer unique advantages in multistep synthesis.
(2-methoxyphenyl)dimethylsilyl lithium and cuprate reagents offer unique advantages in multistep synthesis.
Organic letters (2001-10-12)
T W Lee, E J Corey
PMID11594828
ABSTRACT
[structure: see text]. The new silyllithium reagent 1 and the corresponding cyanocuprate 3 are readily generated under optimal conditions and are useful for the formation of C-Si bonds. Tamao-Fleming oxidation of such C-Si bonds can be effected under very mild conditions.
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