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07-3750

Sigma-Aldrich

Diiodomethane

SAJ first grade, ≥98.0%

Synonym(s):

Methylene iodide

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About This Item

Empirical Formula (Hill Notation):
CH2I2
CAS Number:
75-11-6
Molecular Weight:
267.84
Beilstein:
1696892
EC Number:
200-841-5
MDL number:
MFCD00001079
UNSPSC Code:
12352101
PubChem Substance ID:
329748419

grade

SAJ first grade

vapor density

9.25 (vs air)

Assay

≥98.0%

form

liquid

availability

available only in Japan

bp

67-69 °C/11 mmHg (lit.)

mp

5-8 °C (lit.)

density

3.325 g/mL at 25 °C (lit.)

SMILES string

ICI

InChI

1S/CH2I2/c2-1-3/h1H2

InChI key

NZZFYRREKKOMAT-UHFFFAOYSA-N

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Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H412

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

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Yan Li et al.
Colloids and surfaces. B, Biointerfaces, 75(2), 550-556 (2009-10-24)
The self-assembled monolayers (SAMs) with gradient surface free energies were prepared by surface grafting of a binary mixture of methyl and vinyl terminated trimethoxysilanes on hydrophilic glass slides followed by in situ oxidation of vinyl groups into carboxyl groups. Characterized
Razak Kadir et al.
Environmental science & technology, 43(13), 5113-5116 (2009-08-14)
An optical sensor sensitive to BTX has been developed by spin coating a thin film of polyacrylate resin onto a tin- diffused glass optical waveguide. A pair of prism coupler was employed for optical coupling matched with diiodomethane (CH2l2). The
Kevin Cheng et al.
Organic letters, 13(9), 2346-2349 (2011-04-06)
A diastereoselective synthesis of trans-2-substituted cyclopropanols is outlined. Bimetallic CH(2)(ZnI)(2) was found to react with α-chloroaldehydes to give cyclopropanols in yields of 64-89% and dr's ≥ 10:1. The high trans-selectivity resulted from equilibration of the cyclopropoxide intermediates.
T S Meiron et al.
Journal of food science, 72(9), E485-E491 (2007-11-24)
Food adhesion is an important attribute that could have both positive and negative ramifications depending on the application. Yet, its quantification remains cumbersome and as a consequence adhesion models are scarce. The effect of surface roughness, free energy, and ozone
Shaoliang Zhang et al.
Physical chemistry chemical physics : PCCP, 13(24), 11671-11677 (2011-05-20)
Flash photolysis (FP) coupled to resonance fluorescence (RF) was used to measure the absolute rate coefficients (k(1)) for the reaction of OH(X(2)Π) radicals with diiodomethane (CH(2)I(2)) over the temperature range 295-374 K. The experiments involved time-resolved RF detection of the
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