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  • Highly efficient isobutyraldehyde-mediated epoxidation of cyclic alkenes with dioxygen catalyzed by a novel dimeric manganese(II) complex containing an easy-to-prepare flexible carboxamide ligand.

Highly efficient isobutyraldehyde-mediated epoxidation of cyclic alkenes with dioxygen catalyzed by a novel dimeric manganese(II) complex containing an easy-to-prepare flexible carboxamide ligand.

Inorganic chemistry (2009-05-28)
Hamid Reza Khavasi, Koroush Sasan, Mahtab Pirouzmand, Samad Nejad Ebrahimi
ABSTRACT

Dioxygen epoxidation of cyclic alkenes into their corresponding epoxides was successfully achieved in good yield by using a novel binuclear manganese carboxamide complex as the catalyst and isobutyraldehyde as the cosubstrate.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Isobutyraldehyde, natural, 96%, FG
Sigma-Aldrich
Isobutyraldehyde, 98%
Sigma-Aldrich
Isobutyraldehyde, ≥99%
Sigma-Aldrich
Isobutyraldehyde, dry, 98%
Sigma-Aldrich
Isobutyraldehyde, redistilled, ≥99.5%
Sigma-Aldrich
Isobutyraldehyde, ≥98%, FG