714836
Iodine monochloride solution
1 M in acetic acid
Synonym(s):
Chloroiodide solution, Wijs solution
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About This Item
Linear Formula:
ICl
CAS Number:
Molecular Weight:
162.36
Beilstein:
3587194
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
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form
solution
concentration
1 M in acetic acid
density
1.143 g/mL at 25 °C
SMILES string
ClI
InChI
1S/ClI/c1-2
InChI key
QZRGKCOWNLSUDK-UHFFFAOYSA-N
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General description
Iodine monochloride is an inorganic reagent used in the iodination and chloroiodination of aromatic and unsaturated compounds, respectively. It is also used to cleave carbon-metal bonds.
Application
Iodine monochloride can be used:
- As a reagent in the preparation of α-iodo β-ketosulfones from β-ketosulfones.
- In the synthesis of 3-(4-bromo-2-methylphenyl)-4-iodosydnone, which is further used to prepare substituted pyrazoles.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
105.1 °F
Flash Point(C)
40.6 °C
Certificates of Analysis (COA)
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The removal of Hg(0) by the homogenous gas-phase reaction and particle-induced reaction was investigated under various conditions. Iodine monochloride was found to be efficient for Hg(0) oxidation, with the apparent 2nd-order rate constant of about 10.5(±0.3)×10(-17) cm(3) molecules(-1) s(-1) and
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