Skip to Content
Merck
All Photos(1)

Documents

306789

Sigma-Aldrich

5,10,15,20-Tetrakis(4-trimethylammoniophenyl)porphyrin tetra(p-toluenesulfonate)

Dye content 90 %

Synonym(s):

TTMAPP

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C84H90N8O12S4
CAS Number:
69458-20-4
Molecular Weight:
1531.92
Beilstein:
6378804
MDL number:
MFCD00012023
UNSPSC Code:
12161600
PubChem Substance ID:
24858498
NACRES:
NA.22

form

powder

composition

Dye content, 90%

reaction suitability

core: porphyrin
reaction type: Photocatalysis
reagent type: catalyst

SMILES string

Cc1ccc(cc1)S([O-])(=O)=O.Cc2ccc(cc2)S([O-])(=O)=O.Cc3ccc(cc3)S([O-])(=O)=O.Cc4ccc(cc4)S([O-])(=O)=O.C[N+](C)(C)c5ccc(cc5)-c6c7ccc(n7)c(-c8ccc(cc8)[N+](C)(C)C)c9ccc([nH]9)c(-c%10ccc(cc%10)[N+](C)(C)C)c%11ccc(n%11)c(-c%12ccc(cc%12)[N+](C)(C)C)c%13ccc6[nH]%13

InChI

1S/C56H62N8.4C7H8O3S/c1-61(2,3)41-21-13-37(14-22-41)53-45-29-31-47(57-45)54(38-15-23-42(24-16-38)62(4,5)6)49-33-35-51(59-49)56(40-19-27-44(28-20-40)64(10,11)12)52-36-34-50(60-52)55(48-32-30-46(53)58-48)39-17-25-43(26-18-39)63(7,8)9;4*1-6-2-4-7(5-3-6)11(8,9)10/h13-36,57,60H,1-12H3;4*2-5H,1H3,(H,8,9,10)/q+4;;;;/p-4/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-;;;;

InChI key

XFCJLTPKCPNBQV-BHYUYDJESA-J

Looking for similar products? Visit Product Comparison Guide

Application

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Jianhua Liu et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 67(2), 455-459 (2007-01-27)
A kinetic method performed on a flow injection system is described for the determination of ascorbic acid by using its catalytic effect on the complexation reaction of Cu(II) with 5,10,15,20-tetrakis(4-N-trimethyl-aminophenyl)porphyrin. The characteristic spectrum of porphyrin (Soret band), which shows intense
T Makino et al.
Clinica chimica acta; international journal of clinical chemistry, 111(1), 1-8 (1981-03-19)
A colorimetric method is presented for the accurate determination of serum copper in 0.1 ml sized samples, using alpha, beta, gamma, delta-tetrakis(4-N-trimethylaminophenyl)porphine. This new reagent has high sensitivity (epsilon 433nm = 5.1 X 10(5) l.mol--1.cm--1), it is water-soluble and has
Izabela Hanyz et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 1(2), 126-132 (2003-03-28)
We have studied the influence of solvent acidity on the aggregation/protonation behaviour of two charged tetraphenylporphyrins: positively charged tetrakis(N,N,N-trimethylanilinium-4-yl)porphyrin (TAP) and negatively charged tetrakis(4-sulfonatophenyl)porphyrin (TPPS4). Spectroscopic measurements (absorption, fluorescence, excitation and photoacoustic) have been made to follow the radiative and
T Makino
Clinica chimica acta; international journal of clinical chemistry, 282(1-2), 65-76 (1999-05-26)
A direct colorimetric method is presented for simple and sensitive determination of serum zinc in 0.05-ml samples, using a cationic porphyrin, alpha,beta,gamma,delta-tetrakis(4-N-trimethylaminophenyl) porphine tetratoluenesulfonate salt (ttmapp, epsilon = 41.5 x 10(4) l/mol per cm at 421 nm). 7-Iodo-8-hydroxyquinoline-5-sulfonic acid (Ferron)
C Nakamura et al.
Biosensors & bioelectronics, 16(9-12), 1095-1100 (2001-10-27)
In this paper the development and feasibility of a novel detection system for a low molecular weight chemical, in which a peptide was utilized as a binding molecule, are described. Surface plasmon resonance (SPR) apparatus was used as a transducer.
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service