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32824

Supelco

Fluazifop

PESTANAL®, analytical standard

Sinónimos:

2-[4-(5-Trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid

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About This Item

Fórmula empírica (notación de Hill):
C15H12F3NO4
Número de CAS:
69335-91-7
Peso molecular:
327.26
Beilstein/REAXYS Number:
552236
MDL number:
MFCD00270159
UNSPSC Code:
41116107
PubChem Substance ID:
329754341
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CC(Oc1ccc(Oc2ccc(cn2)C(F)(F)F)cc1)C(O)=O

InChI

1S/C15H12F3NO4/c1-9(14(20)21)22-11-3-5-12(6-4-11)23-13-7-2-10(8-19-13)15(16,17)18/h2-9H,1H3,(H,20,21)

InChI key

YUVKUEAFAVKILW-UHFFFAOYSA-N

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General description

Fluazifop is one of the major metabolites of fluazifop-p-butyl, a systemic, post-emergence herbicide used for the control of annual and perennial grass weeds in non-graminaceous crops.

Application

Fluazifop may be used as an analytical reference standard for the determination of the analyte in:
  • Rainwater samples by solid-phase extraction (SPE) and liquid chromatography-tandem mass spectrometry (LC-MS/MS).
  • Vegetables by acetonitrile-based QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction followed by LC-MS/MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardEnvironment
GHS08,GHS09

signalword

Warning

hcodes

H361,H400

Hazard Classifications

Aquatic Acute 1 - Repr. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
BCCM2541
BCCL7575
BCCF7942
BCCB6532
BCBX4129

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Visite la Librería de documentos

Grazyna Kostka et al.
Toxicology, 178(3), 221-228 (2002-08-09)
The aim of this study was to determine the effect of herbicide fluazifop, on the early occurring changes in rat liver regarded as hepatic markers of peroxisome proliferators (PPs). Fluazifop was administered orally to male Wistar rats at increasing doses
K A Walker et al.
The Biochemical journal, 254(3), 811-817 (1988-09-15)
Concentrations of fluazifop-butyl sprayed on intact plants caused large decreases in the incorporation of radioactivity from [1-14C]acetate into lipids of barley (Hordeum vulgare) leaves and stems, but did not affect leaves or stems of pea (Pisum sativum). Labelling of all
Validation and uncertainty study of a comprehensive list of 160 pesticide residues in multi-class vegetables by liquid chromatography-tandem mass spectrometry.
Kmellar B, et al.
Journal of Chromatography A, 1215(1-2), 37-50 (2008)
A M Shestopalov et al.
Journal of combinatorial chemistry, 2(1), 24-28 (2000-04-06)
S-Alkylation followed by heterocyclization of trifluoromethyl-3-cyano-2(1H)-pyridinethiones was used for preparation of libraries of S-alkyl trifluoromethylpyridines and thieno[2,3-b]pyridines. The S-alkylation (in water--DMF mixtures) was successful for all 18 alkylating agents employed (yields typically > 50%). S-Alkyl derivatives were further converted to
Ahmed A Tantawy
Journal of the Egyptian Society of Parasitology, 32(3), 837-847 (2003-01-07)
The herbicides, Butachlor and Fluazifop-p-butyl were evaluated against B. alexandrina and their infection with S. mansoni, as well as against the miracidia and cercariae. The tested herbicides reduced the survival and infection rates of B. alexandrina by 28% and 35.71%
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