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Merck

F6129

Sigma-Aldrich

Iron(III) citrate

technical grade

Sinónimos:

Ferric citrate, Iron(III) citrate, Iron(III) citrate hydrate

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About This Item

Fórmula empírica (notación de Hill):
C6H5FeO7
Número de CAS:
Peso molecular:
244.94
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

technical grade

form

powder

composition

Fe, 16.5-18.5%

technique(s)

cell culture | mammalian: suitable

application(s)

battery manufacturing

SMILES string

OC12CC(=O)O[Fe](OC(=O)C1)OC2=O

InChI

1S/C6H8O7.Fe/c7-3(8)1-6(13,5(11)12)2-4(9)10;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);/q;+3/p-3

InChI key

NPFOYSMITVOQOS-UHFFFAOYSA-K

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General description

Iron(III) citrate technical grade is a brown to dark orangepowder. It is soluble in water, but insoluble in most organics includingalcohols. The powder is sensitive to light; like many iron carboxylates, bluelight photo-reduces iron(III) citrate, forming the Fe2+ ion andconcomitantly oxidizing the carboxyl group to yield carbon dioxide. Iron(III)citrate thermally decomposes to α-Fe2O3 at 460 °C.

Application

Iron(III) citrate is a synthetic precursor for iron-containing compounds. It is commonly used to prepare Fe3O4 nanoparticles or Fe3O4-nanocomposites by hydrothermal methods and Fe2O3 materials by thermal decomposition and sol-gel processing. Iron(III) citrate is well-suited to sol-gel processing because of its high solubility in water and low solubility inorganic phases. Consequently, iron(III) citrate is an important precursor in the synthesis of iron-doped and iron-containing metal oxides studied for lithium-ion battery cathodes.

It can also be used in the degradation of tetracycline for the treatment of polluted water.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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P Senthil Kumar et al.
ACS omega, 3(3), 3036-3044 (2018-07-20)
Pristine trivanadate (LiV3O8) and doped lithium trivanadate (LiV3-x M x O8, M = Zn/Co/Fe/Sn/Ti/Zr/Nb/Mo, x = 0.01/0.05/0.1 M) compounds were prepared by a simple reflux method in the presence of the polymer, Pluronic P123, as the chelating agent. For comparison
Jianguo Guan et al.
Chemical communications (Cambridge, England), 46(35), 6605-6607 (2010-08-18)
We present a simple and effective heterogeneous contraction method to fabricate hollow spheres with controllable interior structures (ranging from solid, simple hollow to core-in-hollow-wall, double-wall hollow and core-in-double-hollow-wall spheres) by a non-equilibrium heat-treatment process of gel precursors with a high
Tatsuya Fukushima et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(42), 16829-16834 (2012-10-03)
Citrate is a common biomolecule that chelates Fe(III). Many bacteria and plants use ferric citrate to fulfill their nutritional requirement for iron. Only the Escherichia coli ferric citrate outer-membrane transport protein FecA has been characterized; little is known about other
Akio Iida et al.
American journal of nephrology, 37(4), 346-358 (2013-04-04)
Ferric citrate hydrate (JTT-751) is being developed as a treatment for hyperphosphatemia in chronic kidney disease patients, and shows serum phosphorus-reducing effects on hyperphosphatemia in hemodialysis patients. We examined whether JTT-751 could reduce phosphorus absorption in normal rats and prevent
Marcus J Edwards et al.
Structure (London, England : 1993), 20(7), 1275-1284 (2012-06-12)
Members of the genus Shewanella translocate deca- or undeca-heme cytochromes to the external cell surface thus enabling respiration using extracellular minerals and polynuclear Fe(III) chelates. The high resolution structure of the first undeca-heme outer membrane cytochrome, UndA, reveals a crossed

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