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90660

Sigma-Aldrich

Tribenzylamine

≥99.0% (NT)

Sinónimos:

TBA

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About This Item

Fórmula lineal:
(C6H5CH2)3N
Número de CAS:
620-40-6
Peso molecular:
287.40
Beilstein/REAXYS Number:
2214682
EC Number:
210-638-3
MDL number:
MFCD00004773
UNSPSC Code:
12352100
PubChem Substance ID:
57653401
NACRES:
NA.22

assay

≥99.0% (NT)

form

powder

mp

91-94 °C (lit.)

SMILES string

C(N(Cc1ccccc1)Cc2ccccc2)c3ccccc3

InChI

1S/C21H21N/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2

InChI key

MXHTZQSKTCCMFG-UHFFFAOYSA-N

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Application

Tribenzylamine (TBA) is a tertiary amine which can be used :
  • As a nitrogen group source for the reactions involving C−N bond formation.
  • For the synthesis of imine i.e. N−benzylidene benzylamine by aerobic oxidative condensation.
  • As an extractant for the separation and determination of Cr(VI) and Cr(III) from wastewater.

TBA can also undergo debenzylation in the presence of ceric ammonium nitrate (CAN) to form dibenzylamine.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H317

Hazard Classifications

Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

399.2 °F - closed cup

flash_point_c

204 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análisis (COA)

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Copper-Catalyzed Oxidative Amination of Benzoxazoles via C- H and C- N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources.
Guo S, et al.
Organic Letters, 13(3), 522-525 (2010)
Céline Burnier et al.
Talanta, 192, 135-141 (2018-10-24)
Nowadays, Gas Chromatography Mass Spectrometry (GC-MS) is mainly used in forensic sciences but suffers from limitations when the analysed compounds are thermally instable as it is the case for THC-A (Tetrahydrocannabinolic Acid) which is converted into Δ9-THC (Δ9-Tetrahydrocannabinol) that subsequently
Chemoselective oxidative debenzylation of tertiary N-benzyl amines.
Bull SD, et al.
Chemical Communications (Cambridge, England), 165(5), 337-338 (2000)
Highly active and selective gold catalysts for the aerobic oxidative condensation of benzylamines to imines and one-pot, two-step synthesis of secondary benzylamines.
Grirrane A, et al.
J. Catal., 264(2), 138-144 (2009)
Yan Qu et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 58(9-10), 640-642 (2003-10-28)
Two compounds, (p-methoxyphenyl) diphenylmethanol (1) and tribenzylamine (2), were isolated from Humulus lupulus. Their structures were established on the basis of spectral evidence (MS, IR, NMR, HMBC, HMQC, 1H-1H COSY experiments). Compounds 1 and 2 were found as natural products
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