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709093

Sigma-Aldrich

C60 Pyrrolidine tris-acid ethyl ester

97% (HPLC)

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About This Item

Fórmula empírica (notación de Hill):
C72H19O6N
Peso molecular:
993.92
UNSPSC Code:
12352103
NACRES:
NA.23

Quality Level

100

assay

97% (HPLC)

form

powder

mp

240-245 °C

solubility

chlorobenzene: soluble
organic solvents: soluble
toluene: soluble

SMILES string

CCOC(=O)CN1C(C(=O)OCC)C23c4c5c6c7c8c9c(c%10c%11c2c%12c%13c4c%14c%15c5c%16c7c%17c8c%18c%19c9c%10c%20c%21c%11c%12c%22c%23c%13c%14c%24c%25c%15c%16c%26c%17c%27c%18c%28c%19c%20c%29c%21c%22c%30c%23c%24c%31c%25c%26c%27c%32c%28c%29c%30c%31%32)C36C1C(=O)OCC

Categorías relacionadas

General description

C60 Pyrrolidine tris-acid ethyl ester is a carboxylic ester terminated fulleropyrrolidine that can be used as an electron acceptor in organic electronic devices. It can be potentially used in the fabrication of perovskite solar cells.
Interaction of C60 pyrrolidine tris-acid ethyl ester (PyC60) with bisporphyrin in toluene was investigated.

Application

C60 Pyrrolidine tris-acid ethyl ester may be used to functionalize ZnO nanoparticles, to be used as a cathode buffer layer in solar cells.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

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Anamika Ray et al.
The journal of physical chemistry. A, 115(35), 9929-9940 (2011-07-22)
The present article reports, for the first time, the photophysical aspects of noncovalent interaction of a fullerene derivative, namely, C(60) pyrrolidine tris-acid ethyl ester (PyC(60)) with a series of zincphthalocyanines, for example, underivatized zincphthalocyanine (1), zinc-1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine (2), and zinc-2,3,9,10,16,17,23,24-octakis-(octyloxy)-29H,31H-phthalocyanine (3)
Performance enhancement of inverted polymer solar cells with fullerene ester derivant-modified ZnO film as cathode buffer layer.
Li P, et al.
Solar Energy Mat. and Solar Cells, 126, 36-41 (2014)
Carboxylic ester-terminated fulleropyrrolidine as an efficient electron transport material for inverted perovskite solar cells
Chang J, et al.
Journal of Material Chemistry C, 6(26), 6982-6987 (2018)
Device Physics of the Carrier Transporting Layer in Planar Perovskite Solar Cells
Ren X, et al.
Advanced Optical Materials, 6(26), 1900407-1900407 (2019)
Photophysical investigations on determination of molecular structure and binding strength of supramolecular complexation between fulleropyrrolidine and a designed bisporphyrin in solution.
Mukherjee S, et al.
Spectrochimica Acta Part A: Molecular Spectroscopy, 109, 32-36 (2013)

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