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277681

Sigma-Aldrich

3-Methyl-3-oxetanemethanol

98%

Sinónimos:

3-Hydroxymethyl-3-methyl-oxetane

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About This Item

Fórmula empírica (notación de Hill):
C5H10O2
Número de CAS:
3143-02-0
Peso molecular:
102.13
Beilstein/REAXYS Number:
102773
MDL number:
MFCD00010273
UNSPSC Code:
12352100
PubChem Substance ID:
24856780
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.446 (lit.)

bp

80 °C/40 mmHg (lit.)

density

1.024 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC1(CO)COC1

InChI

1S/C5H10O2/c1-5(2-6)3-7-4-5/h6H,2-4H2,1H3

InChI key

NLQMSBJFLQPLIJ-UHFFFAOYSA-N

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Application

3-Methyl-3-oxetanemethanol has been used in the preparation of:
  • star-shaped copolymer consisting of a hyperbranched poly(3-methyl-3-oxetanemethanol) core and polytetrahydrofuran arms
  • pyridyl disulfide-functionalized cyclic carbonate monomer, required for the synthesis of of functional poly(ε-caprolactone) containing pendant pyridyl disulphide groups
  • δ-lactams

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

206.6 °F - closed cup

flash_point_c

97 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Synthesis of a Star-Shaped Copolymer with a Hyperbranched Poly (3-methyl-3-oxetanemethanol) Core and Tetrahydrofuran Arms by One-Pot Copolymerization.
Hou J and Yan D.
Macromolecular Rapid Communications, 23(8), 456-459 (2002)
Functional poly (e-caprolactone) s via copolymerization of e-caprolactone and pyridyl disulfide-containing cyclic carbonate: controlled synthesis and facile access to reduction-sensitive biodegradable graft copolymer micelles.
Chen W, et al.
Macromolecules, 46(3), 699-707 (2013)
Bhooma Raghavan et al.
The Journal of organic chemistry, 71(5), 2151-2154 (2006-02-25)
A concise, stereoselective synthesis of alpha-substituted gamma-lactams is reported. gamma-Lactam scaffolds 2 and 3, possessing an Evans' chiral auxiliary and two types of N substituents, were successfully alkylated with different electrophiles to give alpha-substituted gamma-lactams with reasonable diastereoselectivities. The use
Gintare Krucaite et al.
Molecules (Basel, Switzerland), 26(7) (2021-04-04)
A group of polyethers containing electroactive pendent 4,7-diarylfluorene chromophores have been prepared by the multi-step synthetic route. Full characterization of their structures has been presented. The polymeric materials represent derivatives of high thermal stability with initial thermal degradation temperatures in

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