Saltar al contenido
Merck
Todas las fotos(2)

Key Documents

View All Documentation

245771

Sigma-Aldrich

Isobutyric anhydride

97%

Sinónimos:

2-Methylpropionic anhydride

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
Todas las fotos(2)

About This Item

Fórmula lineal:
(CH3)2CHCO2COCH(CH3)2
Número de CAS:
97-72-3
Peso molecular:
158.19
Beilstein/REAXYS Number:
386267
EC Number:
202-603-6
MDL number:
MFCD00008913
UNSPSC Code:
12352100
PubChem Substance ID:
24854757
NACRES:
NA.22

vapor density

5.45 (vs air)

vapor pressure

10 mmHg ( 67 °C)

assay

97%

form

liquid

autoignition temp.

624 °F

expl. lim.

1.09 %, 87 °F
7.7 %, 127 °F

refractive index

n20/D 1.406 (lit.)

bp

182 °C (lit.)

mp

−56 °C (lit.)

density

0.954 g/mL at 25 °C (lit.)

SMILES string

CC(C)C(=O)OC(=O)C(C)C

InChI

1S/C8H14O3/c1-5(2)7(9)11-8(10)6(3)4/h5-6H,1-4H3

InChI key

LSACYLWPPQLVSM-UHFFFAOYSA-N

¿Está buscando productos similares? Visita Guía de comparación de productos

Categorías relacionadas

General description

The mechanism of esterification of 1-(1-naphthyl)ethanol by isobutyric anhydride with 4-pyrrolidinopyridine as catalyst was studied.

Application

Isobutyric anhydride was used in the synthesis of 4-O-isobutyryl derivative via reaction with octyl β-D-glucopyranoside in the presence of C2-symmetric chiral 4-pyrrolidinopyridine as a catalyst.

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

154.4 °F - closed cup

flash_point_c

68 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Takeo Kawabata et al.
Journal of the American Chemical Society, 129(42), 12890-12895 (2007-10-02)
An organocatalytic method for the chemo- and regioselective acylation of monosaccharides has been developed. Treatment of octyl beta-D-glucopyranoside with isobutyric anhydride in the presence of 10 mol % of a C2-symmetric chiral 4-pyrrolidinopyridine catalyst (1) at -50 degrees C gave
Evgeny Larionov et al.
Journal of the American Chemical Society, 134(22), 9390-9399 (2012-05-10)
The mechanism of esterification of the secondary alcohol 1-(1-naphthyl)ethanol 9 by isobutyric anhydride catalyzed by 4-pyrrolidinopyridine (PPY, 11) and a series of single enantiomer atropisomeric 4-dialkylaminopyridines 8a-g has been studied computationally at the B3LYP/6-311+G(d,p)//B3LYP/6-31G(d) level. Comparison of the levels of
Bin Wang et al.
Chemistry, an Asian journal, 10(8), 1690-1697 (2015-06-03)
Hyperbranched polyethylenimine terminated with isobutyramide groups (HPEI-IBAm), 4-(phenylazo)benzoic acid (PABA), and α-cyclodextrin (α-CD) were assembled together at pH≈7 to form the three-component supramolecular complexes that were verified by (1) H and 2D ROESY (1) H NMR spectroscopy. UV/Vis spectrometric titration experiments
Xiaoning Shan et al.
International journal of pharmaceutics, 590, 119884-119884 (2020-09-21)
Poly(2-methyl-2-oxazoline) (PMOZ), poly(2-propyl-2-oxazoline) (PnPOZ) and poly(2-isopropyl-2-oxazoline) (PiPOZ) were synthesized by hydrolysis of 50 kDa poly(2-ethyl-2-oxazoline) (PEOZ) and subsequent reaction of the resulting poly(ethylene imine) with acetic, butyric and isobutyric anhydrides, respectively. These polymers were characterized by proton nuclear magnetic resonance, FTIR
Rosamaria Capuano et al.
Bio-protocol, 7(23), e2642-e2642 (2017-12-05)
Human induced pluripotent stem cells (hiPSCs) are a promising tool in cell-based therapies for degenerative diseases. A safe application of hiPSCs in vivo, requires the detection of the presence of residual undifferentiated pluripotent cells that can potentially cause the insurgence

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico