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234451

Sigma-Aldrich

1-Bromohexadecane

97%

Sinónimos:

Cetyl bromide, Hexadecyl bromide

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About This Item

Fórmula lineal:
CH3(CH2)15Br
Número de CAS:
112-82-3
Peso molecular:
305.34
Beilstein/REAXYS Number:
773989
EC Number:
204-008-7
MDL number:
MFCD00000230
UNSPSC Code:
12352100
PubChem Substance ID:
24854042
NACRES:
NA.22

vapor density

10.6 (vs air)

vapor pressure

<1 mmHg ( 20 °C)

assay

97%

refractive index

n20/D 1.461 (lit.)

bp

190 °C/11 mmHg (lit.)

mp

16-18 °C (lit.)

density

0.999 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCCCCCCCBr

InChI

1S/C16H33Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h2-16H2,1H3

InChI key

HNTGIJLWHDPAFN-UHFFFAOYSA-N

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Categorías relacionadas

Application

1-Bromohexadecane has been used:
  • in the preparation of soluble carbon nano-onions by covalent functionalization with hexadecyl chains
  • as extraction solvent in determination of endocrine-disrupting phenols (EDPs) in water samples by ultrasound-assisted emulsification microextraction (MS-USAEME) method
  • in the preparation of [2-(methacryloyloxy)ethyl]dimethylhexadecylammonium bromide monomer, required for the synthesis of novel methacrylate based adsorbents
  • in the synthesis of surfactant, N-hexadecyl ethylenediamine triacetic acid (HED3A)

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315

Hazard Classifications

Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

350.6 °F - closed cup

flash_point_c

177 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

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Agustín Molina-Ontoria et al.
Chemical communications (Cambridge, England), 49(24), 2406-2408 (2013-02-16)
Herein we report the preparation of truly soluble CNOs by covalent functionalization with hexadecyl chains. These compounds are prepared in two steps: first, reduction of CNOs with a Na-K alloy in 1,2-DME under vacuum, followed by nucleophilic substitution employing 1-bromohexadecane.
Ming-Wei Shu et al.
The Analyst, 137(9), 2143-2150 (2012-03-03)
Manual shaking-enhanced, ultrasound-assisted emulsification microextraction (MS-USAEME) combined with ultraperformance liquid chromatography (UPLC) with UV detection has been developed for the determination of five endocrine-disrupting phenols (EDPs) in seawater samples and detergent samples: 4-tert-butylphenol (4-t-BP), 4-cumylphenol (4-CP), 4-tert-octylphenol (4-t-OP), 2,4-di-tert-butylphenol (2,4-di-t-BP)
Xixin Wang et al.
Journal of colloid and interface science, 279(2), 548-551 (2004-10-07)
A new kind of surfactant named N-hexadecyl ethylenediamine triacetic acid (HED3A) was synthesized from anhydrous ethylenediamine, 1-bromohexadecane, and chloroacetic acid. Testing showed stability of HED3A in hard water, wetting power, dispersing power, and surface tension increased along with pH value.
Andreas Håkansson et al.
Journal of colloid and interface science, 374(1), 25-33 (2012-03-01)
The Oil Transfer Technique (OTT) was developed by Taisne et al. [1] to measure coalescence during emulsification and has been applied since in several studies. One of the main drawbacks of this technique is that it only gives a qualitative
Guomin Lin et al.
Molecules (Basel, Switzerland), 25(22) (2020-11-20)
Titanate-based bonding agents are a class of efficient bonding agents for improving the mechanical properties of composite solid propellants, a kind of special composite material. However, high solid contents often deteriorate the rheological properties of propellant slurry, which limits the
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