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Key Documents

742546

Sigma-Aldrich

Hydrogen sulfide solution

0.8 M in THF

Synonym(s):

Dihydrogen monosulfide, Hydrosulfuric acid

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About This Item

Empirical Formula (Hill Notation):
H2S
CAS Number:
Molecular Weight:
34.08
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22

Quality Level

form

liquid

concentration

0.7-0.9 M in THF

suitability

conforms to structure for Proton NMR spectrum

storage temp.

2-8°C

SMILES string

S

InChI

1S/H2S/h1H2

InChI key

RWSOTUBLDIXVET-UHFFFAOYSA-N

Application

Hydrogen sulfide solution can be used in the preparation of lead sulfide (PbS), titanium disulfide(TiS2) and cadmium sulfide (CdS). It is also used as a ligand in the synthesis of ammineruthenium complexes.

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup - Solvent

Flash Point(C)

-17 °C - closed cup - Solvent


Certificates of Analysis (COA)

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Modified Sol-Gel Processing for Titanium Disulfide.
Go, Yong Bok et al.
J. Korean Chem. Soc., 41(3), 130-137 (1997)
Cadmium sulphide quantum dots in morphologically tunable triblock copolymer aggregates.
Duxin, Nicolas et al.
Journal of the American Chemical Society, 127(28), 10063-10069 (2005)
Size variation of PbS particles in high-refractive-index nanocomposites.
Kyprianidou-Leodidou, Tasoula et al.
The Journal of Physical Chemistry, 98(36), 8992-8997 (1994)
Amine Ruthenium complexes of hydrogen sulfide and related sulfur ligands.
Kuehn CC
Journal of the American Chemical Society, 98(3), 689-702 (1976)
Miroslav Lisjak et al.
Plant, cell & environment, 36(9), 1607-1616 (2013-01-26)
Hydrogen sulfide (H₂S) has traditionally been thought of as a phytotoxin, having deleterious effects on the plant growth and survival. It is now recognized that plants have enzymes which generate H₂S, cysteine desulfhydrase, and remove it, O-acetylserine lyase. Therefore, it

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